Abstract Coordination engineering of high-valent Fe(IV)-oxo (FeIV=O) is expected to break the activity-selectivity trade-off of traditional reactive oxygen species. while attempts to regulate the oxidation behaviors of heterogeneous FeIV=O remain unexplored. Here. by coordination engineering of Fe-Nx single-atom catalysts (Fe-Nx SACs). https://fitnessgravesyardes.shop/product-category/small-pulley/